Refined relationship between the position of the fundamental OH stretching and the first overtones for clays     

S.?PetitEmail author  A.?Decarreau  F.?Martin  R.?Buchet 《Physics and Chemistry of Minerals》2004,31(9):585-592

The aim of this paper is to determine a relationship between the wavenumbers of the first OH-stretching overtones (W_2OH) and the wavenumbers of the OH-stretching fundamentals (W_OH) to help to interpret the near-infrared (NIR) spectra. The first overtone (2OH) bands appear at wavenumbers less than twice those of the fundamental bands (OH), due to the anharmonic character of vibrations, X = W_2OH/2 - W_OH, with X being the anharmonicity constant. Talc samples with various crystal chemistries are used to solve the equation and the experimental data are well fitted with X = –85.6 cm^–1. As far as the authors are aware, it is the first time that the anharmonicity constant for the OH-stretching vibrations is determined for phyllosilicates. The anharmonicity constant remains almost unchanged for several types of clay samples. Therefore the relation, established from talc samples because their absorption bands are narrow and their wavenumber range of OH vibrations is wide, can be used for any other clay minerals.  相似文献   

Structure transitions of clay fills in North-Western Bohemia     

V. Herbstov  I. Herle 《Engineering Geology》2009,104(3-4):157-166

  相似文献   

Capability of constitutive models to simulate soils with different OCR using a single set of parameters     

Václav Hájek  David MašínJan Boháč 《Computers and Geotechnics》2009

Incorporation of void ratio as a state variable into constitutive models allows, in principle, to use a single set of parameters for soils with different OCRs. Two sets of experimental data on reconstituted clays are used for evaluation of three constitutive models of different complexity (Modified Cam clay model, 3SKH model, hypoplastic model for clays). Although all the models predict the influence of OCR correctly from the qualitative point of view, quantitative comparison using a suitable scalar error measure reveals merits and shortcomings of different models.  相似文献   

Toward a quick evaluation of the performance of gravity installed anchors in clay: Penetration and keying     

《Applied Ocean Research》2017

Gravity installed anchors (GIAs) are the most recent generation of anchoring solutions to moor floating facilities for deepwater oil and gas developments. Challenges associated with GIAs include predicting the initial embedment depth and evaluating the keying performance of the anchor. The former involves high soil strain rate due to large anchor penetration velocity, while the later influences the subsequent behavior and pullout capacity of the anchor. With the coupled Eulerian–Lagrangian method, three-dimensional large deformation finite element models are established to investigate the penetration and keying of GIAs in non-homogeneous clay. In the penetration model, a modified Tresca soil model is adopted to allow the effects of soil strain rate and strain softening, and user-defined hydrodynamic drag force and frictional resistance are introduced via concentrated forces. In the keying model, the anchor line effects are incorporated through a chain equation, and the keying, diving and pulling out behaviors of the anchor can all be replicated. Parametric studies are undertaken at first to quantify the effects of various factors on the performance of GIAs, especially on the penetration and keying behaviors. Based on the results of parametric studies, fitted formulae are proposed to give a quick evaluation of the anchor embedment depth after the installation, and the shackle horizontal displacement, shackle embedment loss and anchor inclination at the end of the keying. Comparative studies are also performed to verify the effectiveness of the fitted formulae.  相似文献   

Provenance discrimination and Source-to-Sink studies from a dryland fluvial regime： An example from Kachchh,western India     

S. P. PRIZOMWALA  Nilesh BHATT  N. BASAVAIAH 《国际泥沙研究》2014,29(1):99-109

Tracing the sediment delivery from its source terrain to its ultimate sink envisage multiple factors that play a vital role in understanding present day erosional engine.To accomplish this,it is significant to distinguish the variable end-members contributing to the basin.The findings from the study of dryland coastal fluvial regime in Kachchh(Western India),which is one of the end members contributing to the Gulf of Kachchh coast(partial sink) and finally to the Arabian Sea(ultimate sink) have been presented here.Multi-proxy sediment provenance proxies such as grain-size,clay minerals,geochemistry and magnetic minerals have been employed to evaluate the provenance discriminating characteristics of the Kachchh dryland fluvial system and factors influencing them.The results of different proxies indicate that the provenance signatures of uplands are quite characteristic with magnetic susceptibility(χ) values of 20×10~(-7)m~3kg~(-1) and smectite(S)/kaolinite(K) ratio between 0.26 and 0.49.The middle reaches show marked increase in magnetic mineral concentration with χ values(140×10~(-7)m~3kg~(-1))and S/K ratio(4.92),while the estuarine tract shows χ values(80×10~(-7)m~3kg~(-1)),S/K ratio(1.90) and,characteristic heavy minerals(i.e.mica minerals),probably reflect the interplay between land and sea oscillations.Major sources of sediments within catchment scale were identified,viz.,upland sedimentary rocks(Juran and Bhuj Formation sandstone-shale) and middle reaches volcanic(Deccan Trap Formation basalt) rocks.The present study draw cautions in provenance of sediment discrimination in areas influenced by Deccan basalt that has the overwhelming sediment delivery and a comparatively subdued effects of other provenance signatures.The studied proxies of mineralogy of clays,magnetic minerals and geochemistry of heavy and major elements serve as the potential for fingerprint of sediment source regions and hence behold a strong position in source to sink studies globally.  相似文献   

Adsorption of Fluoride on the Raw and Modified Cement Clay          下载免费PDF全文

Ayse Dilek Atasoy  Muge Ozdemir Sahin 《洁净——土壤、空气、水》2014,42(4):415-420

  相似文献   

全风化花岗岩化学及矿物成份在全土和粘粒中的不同表征   总被引：1，自引：0，他引：1  

尚彦军  岳中琦  王思敬  涂新斌 《地质科学》2005,40(1):95-104

对全风化花岗岩化学和矿物成份的测试常用全土和粘粒部分(粒径<2μm)分别进行。业已发现两者由于物质组成和结构特征的差异,对土工程地质性质所起作用不同。本文给出了6个全风化花岗岩样品的全土和粘粒部分筛分法和移液管法测定粒度成份,用X荧光光谱仪做全量化学分析,及XRD矿物学分析的结果。对比这两部分数据发现,属于含砾土的这些样品化学成份的变化同矿物一致,尤其是同粘土矿物成份含量变化很一致。同全岩相比,粘粒化学成份中的SiO₂减少了近50%,K₂O含量也降低,而Al₂O₃、Fe₂O₃和H₂O⁺都明显升高。粘粒中氧化物相对含量升高者居多;全岩矿物成份以石英、粘土矿物和长石为主,粘粒中埃洛石和高岭石占大多数,其次为伊利石;粒度成份、化学成份和矿物含量相关性比较明显的是:石英和角砾正相关,和砂粒负相关,长石和砂粒正相关,粘土矿物含量和Al₂O₃、烧失量(LOI)和埃洛石含量正相关。  相似文献   

Comparative analysis of contributing parameters for rainfall-triggered landslides in the Lesser Himalaya of Nepal   总被引：6，自引：0，他引：6  

Ranjan Kumar Dahal  Shuichi Hasegawa  Minoru Yamanaka  Santosh Dhakal  Netra Prakash Bhandary  Ryuichi Yatabe 《Environmental Geology》2009,58(3):567-586

In the Himalaya, people live in widely spread settlements and suffer more from landslides than from any other type of natural disaster. The intense summer monsoons are the main factor in triggering landslides. However, the relations between landslides and slope hydrology have not been a focal topic in Himalayan landslide research. This paper deals with the contributing parameters for the rainfall-triggered landslides which occurred during an extreme monsoon rainfall event on 23 July 2002, in the south-western hills of Kathmandu valley, in the Lesser Himalaya, Nepal. Parameters such as bedrock geology, geomorphology, geotechnical properties of soil, and clay mineralogy are described in this paper. Landslide modeling was performed in SEEP/W and SLOPE/W to understand the relationship of pore water pressure variations in soil layers and to determine the spatial variation of landslide occurrence. Soil characteristics, low angle of internal friction of fines in soil, medium range of soil permeability, presence of clay minerals in soil, bedrock hydrogeology, and human intervention were found to be the main contributing parameters for slope failures in the region.  相似文献   

地球科学中科技名词“粘土”的规范使用探析   总被引：1，自引：0，他引：1  

张贵丽  程光锁 《山东国土资源》2012,28(7):62-65

"黏"和"粘"的用法一直受到广大科研工作者和科技期刊编辑的广泛关注,通过对不同标准、辞书、字典中"黏土"和"粘土"的使用和解释情况,探讨了"黏土"和"粘土"的使用原则,建议在地学领域使用"粘土"为规范名词。  相似文献   

A new afrograptid (Diplostraca: Estheriellina) from the Lower Cretaceous of southern England     

《Cretaceous Research》2017

The Family Afrograptidae is a ‘conchostracan’ group with multiple radial costae reaching to the umbo on their carapaces. It comprises four described genera: Afrograpta, Camerunograpta, Congestheriella and Graptoestheriella with a total of thirteen described species which are occasionally reported from the Jurassic and the Cretaceous in Africa, Europe and South America (i.e. Afrograpta from the Upper Cretaceous of Cameroon; Camerunograpta from the Jurassic to Cretaceous of Cameroon; Congestheriella from the Jurassic to Upper Cretaceous of the Congo Basin, Brazil, Bulgaria, Venezuela and Argentina; and Graptoestheriella from the Upper Jurassic to Lower Cretaceous of Brazil). A new genus and a new species, Surreyestheria ockleyensis gen. et sp. nov., belonging to the Family Afrograptidae from the Lower Cretaceous (lower Barremian) Upper Weald Clay Formation of Ockley Village, Surrey County, southern England is described in this paper. The new genus mainly differs from the other four genera by the special reticulate ornamentation on its carapace. It indicates that the Family Afrograptidae was more diverse and more widely distributed in the late Mesozoic than previously supposed. Afrograptidae is a special branch of Estheriellina the latter originating in the late Palaeozoic and the former in the early Mesozoic. Afrograptids, as a whole had been widespread across Pangea in the Early Jurassic.  相似文献